Synthesis and crystal and molecular structure of the complex Zn(Phen)(S2COC4H9-i)2

Autor:	S. V. Larionov, R. F. Klevtsova, L. A. Glinskaya, V. N. Kirichenko, T. G. Leonova
Rok vydání:	1997
Předmět:	Solid-state physics Intermolecular force Inorganic Chemistry Crystal chemistry.chemical_compound Crystallography Monomer chemistry Octahedron Atom Materials Chemistry Molecule Orthorhombic crystal system Physical and Theoretical Chemistry
Zdroj:	Journal of Structural Chemistry. 38:116-120
ISSN:	1573-8779 0022-4766
DOI:	10.1007/bf02768816
Popis:	A mixed-ligand complex Zn(Phen)(S2COC4H9-i)2 was synthesized. The single crystals of the complex were studied by X-ray diffractometry. The crystals are orthorhombic, a = 20.053(2), b = 19.272(2), c = 13.203(1) A, Vcdl = 5102.5(8) A3, space group Pcab, Z = 8, dcalc = 1.416 g/cm3, R = 0.059. The structure consists of monomeric molecules in which the coordination polyhedron of the central Zn atom is a distorted octahedron (CN = 6). An analysis of molecular packing and intermolecular distances showed that the molecules related by the symmetry center are involved in pronounced intermolecular interactions.
Databáze:	OpenAIRE
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