Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route

Autor:	Alexey N. Proshin, Denis A. Pankratov, Victor A. Tafeenko, Tatiana P. Trofimova, I. S. Glazkova, Marina A. Orlova
Rok vydání:	2020
Předmět:	Reaction conditions 1h nmr spectroscopy 010405 organic chemistry Chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Chloride 0104 chemical sciences Bismuth Crystallography Elemental analysis medicine Single crystal medicine.drug
Zdroj:	Mendeleev Communications. 30:202-204
ISSN:	0959-9436
DOI:	10.1016/j.mencom.2020.03.024
Popis:	Complexes of Bi iii with 2-aminopyrimidine cations with metal-to-ligand ratios of 1:3 or 2:4 (depending on reaction conditions) were synthesized and characterized by elemental analysis, 1H NMR spectroscopy, and single crystal X-ray crystallography. The possibility of conversion of the latter complex into the former one was demonstrated. The determined cytotoxicity depended on the structure of these complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f803eb25c42d8f043d1f77f8e13418c8 https://doi.org/10.1016/j.mencom.2020.03.024 Zobrazit plný text záznamu Full Text from ScienceDirect