Reduction of matrix effects in ICP-MS by optimizing settings of ion optics

Autor:	K. V. Zhernokleeva, Vasilii K. Karandashev, A. Yu. Leykin
Rok vydání:	2013
Předmět:	Analyte Spectrometer business.industry Chemistry Analytical chemistry chemistry.chemical_element Mass spectrometry Analytical Chemistry Ion Hafnium Optics Inductively coupled plasma business Inductively coupled plasma mass spectrometry Indium
Zdroj:	Journal of Analytical Chemistry. 69:22-30
ISSN:	1608-3199 1061-9348
Popis:	The effect of ion optics settings on the degree of suppression of analyte signals due to the presence of different basic elements in a sample solution, such as manganese, copper, indium, lanthanum, hafnium, and lead, was investigated on an example of an XSeries II inductively coupled plasma mass spectrometer. The effect of atomic mass and the concentration of the matrix element on the optimum values of ion optics settings and the change in the analyte signals was studied. It was shown that a decrease in the potential of the extractor lens to −300 V can significantly reduce the matrix effect. As an example, the results of determining impurity elements in solutions containing up to 1 g/L of lanthanum were obtained using standard settings of the spectrometer with a reduced voltage on the extractor. It was shown that the optimization of ion optics settings enables the use of more concentrated solutions, thus reducing the detection limits for elements by several times.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f7e0a4d433f5c90dcb28f65b800357c3 https://doi.org/10.1134/s1061934814010092 Zobrazit plný text záznamu Full text from SpringerLink