Toward highly fluorescent polythiophenes: head-to-tail coupled copolymers of 3-(methoxyethoxyethoxymethyl)thiophene and 3-(perfluoroalkyl)thiophene
| Autor: | Richard L. Pilston, Richard D. McCullough |
|---|---|
| Rok vydání: | 2000 |
| Předmět: |
chemistry.chemical_classification
Materials science Mechanical Engineering Metals and Alloys Grignard reaction Polymer Conjugated system Condensed Matter Physics Photochemistry Fluorescence Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Mechanics of Materials Polymer chemistry Materials Chemistry Copolymer Thiophene Polythiophene Luminescence |
| Zdroj: | Synthetic Metals. :433-436 |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/s0379-6779(99)00393-8 |
| Popis: | The introduction of stiff, polyfluorinated side-chains onto regioregular polymers and copolymers of thiophene could lead to highly luminescent materials. Additionally, this class of conjugated polymers could self-assemble by the fluorophobic effect, leading to interesting new materials. The synthesis and characterization of these polymers is presented. Initial results indicate that these polythiophenes are highly fluorescent relative to poly(3-alkylthiophenes). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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