Laccase-mediated polymerization of 3,4-ethylenedioxythiophene (EDOT)

Autor:	Galina Shumakovich, Alexander I. Yaropolov, Grigory Otrokhov, Olga Morozova, Dmitry Pankratov, I. S. Vasil’eva
Rok vydání:	2012
Předmět:	Laccase biology Chemistry Process Chemistry and Technology Infrared spectroscopy Bioengineering Trametes hirsuta Photochemistry biology.organism_classification Biochemistry Redox Catalysis Polymerization PEDOT:PSS Fourier transform infrared spectroscopy
Zdroj:	Journal of Molecular Catalysis B: Enzymatic. 81:66-68
ISSN:	1381-1177
DOI:	10.1016/j.molcatb.2012.05.008
Popis:	The oxidative polymerization of 3,4-ethylenedioxythiophene (EDOT) has been carried out using laccase-mediator system. High redox potential laccase isolated from fungi Trametes hirsuta catalyzed the reaction of EDOT oxidation. In this reaction laccase used atmospheric oxygen as the terminal oxidant. Potassium octocyanomolybdate(4+) served as high potential redox mediator. The increase in the rate of EDOT oxidation occurs due to laccase catalysis of octocyanomolybdate(4+) ion to octocyanomolybdate(5+). A template method synthesis of EDOT oligomers with poly(2-acrylamido-2-methyl-1-propanesulfonic) acid (PAMPS) was used. The water dispersible oligoEDOT/PAMPS complex was characterized by UV–vis, Fourier transformed infrared spectra and transmission electron microscopy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f7db70e3217787799e4063b782e91fba https://doi.org/10.1016/j.molcatb.2012.05.008 Zobrazit plný text záznamu Full Text from ScienceDirect