Transient formation of N-alkylhemins during hemin-catalyzed epoxidation of norbornene. Evidence concerning the mechanism of epoxidation
| Autor: | Beth E. Dunlap, Andrew R. Miksztal, Teddy G. Traylor, Taku Nakano |
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| Rok vydání: | 1987 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification Bicyclic molecule Alkene General Chemistry Metallacycle Alkylation equipment and supplies Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry Hydrocarbon chemistry Polymer chemistry polycyclic compounds heterocyclic compounds Norbornene Hemin |
| Zdroj: | Journal of the American Chemical Society. 109:3625-3632 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja00246a019 |
| Popis: | During the course of hemin-catalyzed epoxidation of norbornene and other alkenes, the hemin catalyst is converted to N-alkylhemin by addition to the alkene. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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