Der Mechanismus der Alken-Ozonolyse– eine kritische Betrachtung

Autor:	Kurt Schank
Rok vydání:	2004
Předmět:	chemistry.chemical_classification Reaction mechanism Ozonolysis Chemistry Alkene Stereochemistry Organic Chemistry Biochemistry Catalysis Critical examination Inorganic Chemistry Computational chemistry Mechanism (philosophy) Drug Discovery Physical and Theoretical Chemistry High electron
Zdroj:	Helvetica Chimica Acta. 87:2074-2084
ISSN:	1522-2675 0018-019X
Popis:	The Mechanism of Alkene Ozonolysis – a Critical Examination. Alkene ozonolyses have been carried out in experimental organic chemistry for more than a century, and a lucid description of the underlying reaction mechanism has been developped and integrated in most chemistry textbooks. Nevertheless, there are a great number of exceptions hard to rationalize by the accepted mechanism. Attempts in the past to give more-convincing answers to this problem failed. Therefore, the search for an alternative mechanistic model without contradictions is compelling. The present paper offers a redox model based upon the known properties of ozone both as a strong oxidant and an O-atom-transferring agent, especially when reacted with alkenes of sufficiently high electron density to act as reducing partners.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f7b859d6b6d28e946e33321e7f613005 https://doi.org/10.1002/hlca.200490186 Zobrazit plný text záznamu Plný text