Mass spectrometry of organic compounds in the group V elements—I: Straight chain aliphatic derivatives

Autor:	V. G. Plekhanov, R. G. Kostyanovsky
Rok vydání:	1972
Předmět:	Crystallography Fragmentation (mass spectrometry) Straight chain Chemistry Metastability Analytical chemistry Mass spectrum Molecular Medicine Mass spectrometry Instrumentation Biochemistry Spectroscopy Spectral line
Zdroj:	Organic Mass Spectrometry. 6:1183-1198
ISSN:	1096-9888 0030-493X
Popis:	Comparative investigations of the mass spectra of eEH2, Me2EH, Et2EH(E = N, P); Me3E, Et3E(E = N, P, As, Sb, Bi). (n-Pr)3E(E = Sb, Bi); (n-Bu)3E(E = P, As); (n-C5H11)3As and (n-C6H13)3As as well as Et2AsBr have been carried out. Deuteroanalogues, metastable transitions and low voltage spectra were used for elucidation of the fragmentation paths. The mass spectra of MeN(CH2)2 and CD3N(CH2)2 were studied to analyse the structure of the fragments. The main degradation path of amines, i.e. α-cleavage, was shown to be untypical for P, As, Sb and Bi derivatives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f7b2e02603a046fc12602f07cf8b8aba https://doi.org/10.1002/oms.1210061104 Zobrazit plný text záznamu Plný text