Design, synthesis and properties of a trinuclear copper(I) cluster with a triazenide ligand

Autor:	Li-jun Han, Wen-Jun Lei, Xing-wu Tan, Bai-tao Li, Shu-Zhong Zhan
Rok vydání:	2010
Předmět:	Ligand chemistry.chemical_element Crystal structure Copper Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Benzothiazole Materials Chemistry Methanol Physical and Theoretical Chemistry Triazene Luminescence Benzene
Zdroj:	Inorganic Chemistry Communications. 13:1325-1328
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2010.07.027
Popis:	The reaction of methyl anthranilate, sodium nitrite, and 2-aminobenzothiazole produces a new triazenide, namely, 1-[(2-carboxymethyl) benzene]-3-[benzothiazole]triazene (HL). In the presence of Et3N, the reaction of HL and CuCl in THF/methanol gives a trinuclear copper(I) cluster [Cu3L3] THF CH3OH (1 THF CH3OH), which has been characterized by X-ray crystallography, cyclic voltammogram and emission spectrum. CV of 1 reveals two reversible waves at –0.06 and 0.83 V, which correspond to two one-electron oxidation of Cu3 units ([Cu3]4+/[Cu3]3+) and ([Cu3]5+/[Cu3]4+), respectively. 1 appears photoluminescent (λmax = 502 nm) at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f7aab73a4eaaa51b08009013da03b2e7 https://doi.org/10.1016/j.inoche.2010.07.027 Zobrazit plný text záznamu Full Text from ScienceDirect