Structural Features of Uranyl Hydroxylaminate and Oximate Complexes
| Autor: | A. G. Beirakhov, A. V. Rotov |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
inorganic chemicals
Tris Ligand Materials Science (miscellaneous) chemistry.chemical_element Uranium 010402 general chemistry 010403 inorganic & nuclear chemistry Uranyl Ring (chemistry) 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Deprotonation Hydroxylamine chemistry Polymer chemistry Chelation Physical and Theoretical Chemistry |
| Zdroj: | Russian Journal of Inorganic Chemistry. 63:1689-1703 |
| ISSN: | 1531-8613 0036-0236 |
| DOI: | 10.1134/s0036023618130028 |
| Popis: | On the basis of the currently available uranyl complexes with hydroxylamine and its N-substituted derivatives and oximes, the coordination modes of the ligands and structural features of such complexes have been considered with the aim of determining general trends for this new family of uranium(VI) compounds. All the uranyl oximate and hydroxylaminate complexes contain a deprotonated ligand coordinated to the central atom through the nitrogen and oxygen atoms to form a stable three-membered chelate ring. Depending on the composition, these compounds can be divided into two large groups: complexes with tris(chelate) and bis(chelate) structural moieties. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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