Hydrogen Terminated Silicon Nanopowders: Gas Phase Synthesis, Oxidation Behaviour, and Si-H Reactivity

Autor: J. Heimfarth, Klaus Bohmhammel, Peter Fröhlich, Gerald Ziegenbalg, Edwin Kroke, Ute Singliar, A. Müller, C. Sprung, Florian Mertens, C. Schubert, J. Erler, Gerhard Roewer, Jürgen Seidel, Carsten Pätzold, Martin Bertau
Rok vydání: 2014
Předmět:
Zdroj: Silicon. 7:31-42
ISSN: 1876-9918
1876-990X
DOI: 10.1007/s12633-014-9206-2
Popis: Silicon nanopowders were prepared by hot-wire chemical vapour deposition (CVD) from monosilane. Wire materials including Hf, Nb, Ta, Mo, W, Rh, Re, Ir, Pd, and Pt were tested. The filament temperature was varied in the range of 400–2000 ℃ and pressures between 1.0–1.5 bar. Products were characterised by bulk elemental analysis and a laser granulometer. The powders were investigated by TG-DSC-MS under inert, O2, and H2O containing atmosphere, respectively, in a temperature range of 20–700 ℃. Hydrogen evolution occurred in three separate steps, depending on the applied gas atmosphere. The oxidation mechanism was explored by the characteristic OxSi-H bands (x = 0–3) observed in ex situ DRIFT experiments. The oxidation of hydrogen terminated silicon surfaces was investigated employing oxygen (O2), hydrogen peroxide (H2O2), permanganate (MnO\(_{4}^{-}\)), or peroxodisulfate \(\left (\mathrm {S}_{2}\mathrm {O}_{8}^{2-}\right )\) in a temperature range of 0–120 ℃. The oxidation was stepwise and strongly enhanced after pretreatment by alkyl lithium salts or Grignard reagents.
Databáze: OpenAIRE
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