Dramatic persistence (minutes) of the triplet excited state and efficient singlet oxygen generation for C60 incorporated in Y zeolite and MCM-41 silicate

Autor:	Maria S. Galletero, Hermenegildo García, José L. Bourdelande
Rok vydání:	2003
Předmět:	chemistry.chemical_compound Fullerene chemistry MCM-41 Singlet oxygen Excited state General Physics and Astronomy Diffuse reflection Physical and Theoretical Chemistry Triplet state Photochemistry Zeolite Silicate
Zdroj:	Chemical Physics Letters. 370:829-833
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(03)00203-3
Popis:	The triplet excited state of C 60 ( λ max =780 nm) lives minutes and can be monitored by conventional spectrophotometers when this fullerene is incorporated inside LiY, as opposed to C 60 @HY and C 60 @MCM-41 wherein C 60 triplet lives in the submillisecond time scale. C 60 adsorbed in LiY or MCM-41 efficiently generates 1 O 2 that was detected by its characteristic NIR emission (λ em =1270 nm ) .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f7899d327feea0de05fe2ac6864a947f https://doi.org/10.1016/s0009-2614(03)00203-3 Zobrazit plný text záznamu Full Text from ScienceDirect