CoII and RhI complexes with C 2-symmetric chiral diamines of the dioxolane series

Autor:	Bagrat A. Shainyan, Nina N. Chipanina, V. K. Turchaninov, M. V. Ustinov, L. O. Nindakova
Rok vydání:	2005
Předmět:	1h nmr spectroscopy Diene Stereochemistry Infrared spectroscopy General Chemistry Nuclear magnetic resonance spectroscopy Medicinal chemistry Metal chemistry.chemical_compound chemistry Dioxolane visual_art visual_art.visual_art_medium Molecule
Zdroj:	Russian Chemical Bulletin. 54:2343-2347
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-006-0120-7
Popis:	The reaction of di-μ-chlorobis(1,5-cyclooctadiene)dirhodium with (4S, 5S)-2,2-dimethyl-4,5-bis(methylaminomethyl)-1,3-dioxolane (1) gave the complex [Rh(cod)(1)]Cl (cod is 1,5-cyclooctadiene). The composition of the complexes CoCl2 · L2 and [Rh(cod)(L2)]X (L2 = 1, (4S,5S)-2,2-dimethyl-4,5-bis(aminomethyl)-1,3-dioxolane, and (4S, 5S)-2,2-dimethyl-4,5-bis(dimethylaminomethyl)-1,3-dioxolane; X = Cl, TfO) was studied using IR and 1H NMR spectroscopy. In the RhI cyclooctadienediamine complexes, the diene molecule forms a stronger bond with the metal atom than that in the cyclooctadienediphosphine analogs.
Databáze:	OpenAIRE
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