Syntheses of the fungicide/insecticide allosamidin and a structural isomer

Autor:	Robert J. Ferrier, Regine Blattner, Anna-Karin Tidén, Timothy Kemmitt, Richard H. Furneaux, Peter C. Tyler
Rok vydání:	1994
Předmět:	carbohydrates (lipids) Fungicide Biological test chemistry.chemical_compound Allosamizoline Chemistry Stereochemistry Chitin metabolism Structural isomer Disaccharide Cyclopentene Organic chemistry Derivative (chemistry)
Zdroj:	J. Chem. Soc., Perkin Trans. 1. :3411-3421
ISSN:	1364-5463 0300-922X
DOI:	10.1039/p19940003411
Popis:	A synthesis of the naturally occurring inhibitor of chitin metabolism, allosamidin 1, involves, as the key step, condensation between the allosamizoline derivative 39, prepared following oxyamination of the cyclopentene 19, and the disaccharide glycosylating agent 54 which was synthesised from 2-acetamido-2-deoxy-D-glucose. The structural isomer 59 of allosamidin is also reported. Brief biological test results obtained using isomers 1 and 59 are recorded.
Databáze:	OpenAIRE
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