Synthesis and characterization of two Cd (II) complexes constructed with tricarboxylic acids and as a fluorescent probe of iron ions
| Autor: | Xin Liu, Lingshu Meng, Changjiang Zhao, Lun Zhao |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Tricarboxylic acid Polymer 010402 general chemistry 01 natural sciences Fluorescence 0104 chemical sciences Inorganic Chemistry Solvent Crystallography chemistry.chemical_compound chemistry Materials Chemistry Cadmium nitrate Physical and Theoretical Chemistry Powder diffraction Benzoic acid Monoclinic crystal system |
| Zdroj: | Inorganica Chimica Acta. 486:48-54 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2018.10.029 |
| Popis: | Tricarboxylic acid 3,5-bis(-carboxy-phenoxy) benzoic acid (H3BCPBA) 1,5-bis(imidazol-l-yl)-benzene(bib) ligands and cadmium nitrate were used to synthesize two new metal–organic frameworks with different structure under the hydrothermal and solvent thermal conditions, namely [Cd(HBCPBA)(bip)]n (1) and [Cd2(HBCPBA)2(bip)0.5]n (2). We determined the structure of two metal-organic frameworks by XRD, and characterized their structures by TG and powder X-ray diffraction (PXRD). Also we tested the fluorescence properties of the two coordination polymers at room temperature. The results showed the Complex 1 crystallizes in the Hexagonal space group P65, with tentacle structure. Complex 2 crystallizes in the Monoclinic space group P21/c, with a layer of three interdigitated structure. Fluorescence test results show that these two complexes can be used as fluorescent probes to selectively detect and identify Fe3+ ions in water. |
| Databáze: | OpenAIRE |
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