A nanocage-based copper-pentacarboxylate framework for the selective capture of C2H2 and purification of nature gas

Autor:	Ling-Zhi Lv, Hui-Min Zeng, Cai-Hong Zhan, Yun-Long Feng, Wei-Hong Wu, Zhan-Guo Jiang, Chao Wang
Rok vydání:	2021
Předmět:	Ligand chemistry.chemical_element Copper Inorganic Chemistry chemistry.chemical_compound Adsorption Nanocages Petrochemical Chemical engineering Acetylene chemistry Materials Chemistry Metal-organic framework Physical and Theoretical Chemistry Pentacarboxylate
Zdroj:	Inorganica Chimica Acta. 527:120553
ISSN:	0020-1693
DOI:	10.1016/j.ica.2021.120553
Popis:	Selective capture of C2H2 and purification of nature gas exert great influence in our modern life and petrochemical industry. In this research, a novel 3D metal organic framework [Cu5L2(H2O)5]∙10DMA constructed by flexible ligand and Cu (II) was obtained via solvothermal. The adsorption property of this material was studied. The maximum adsorption capacity for N2 is 425.3 cm3 g−1 under the 77 K and 1 atm, which corresponds to the specific surface areas of 1560 m2 g−1. At 278 K, its absorption capacity towards C2H2, CO2 and CH4 are 132.7, 90.2 and 25.8 cm3 g−1, respectively. The high ability to capture acetylene makes it possible to be used to separate and purify gas mixtures C2H2/CH4 and CO2/CH4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f739f7875eb3178a2c804819589a1087 https://doi.org/10.1016/j.ica.2021.120553 Zobrazit plný text záznamu Full Text from ScienceDirect