Vicinal and on-axis surfaces of 6H-SiC(0001) thin films observed by scanning tunneling microscopy

Autor: John F. Wendelken, R. Scott Kern, Jun Xu, Satoru Tanaka, Robert F. Davis
Rok vydání: 1996
Předmět:
Zdroj: Surface Science. 350:247-253
ISSN: 0039-6028
DOI: 10.1016/0039-6028(95)01105-6
Popis: Surfaces of 6H-SiC(0001) homoepitaxial layers deposited on vicinal (∼3.5° off (0001) towards [1120]) and on-axis 6HSiC wafers by chemical vapour deposition have been investigated using ultra-high vacuum scanning tunneling microscopy. Undulating step configurations were observed on both the on-axis and the vicinal surfaces. The former surface possessed wider terraces than the latter. Step heights on both surfaces were ∼0.25 nm corresponding to single bilayers containing one Si and one C layer. After annealing at T >1100°C for 3–5 min in UHV, selected terraces contained honeycomb-like regions caused by the transformation to a graphitic surface as a result of Si sublimation. A model of the observed step configuration has been proposed based on the observation of the [2110] or [1210] orientations of the steps and energetic considerations. Additional deposition of very thin (∼2 nm) SiC films on the above samples by gas source molecular beam epitaxy was performed to observe the evolution of the surface structure. Step bunching and growth of 6HSiC layers and formation of 3CSiC islands were observed on the vicinal and the on-axis surfaces, respectively, and controlled by the diffusion lengths of the adatoms.
Databáze: OpenAIRE