Influence of Pore Structure of Silica Coated on Copper-Zinc Oxide-Based Catalyst for Carbon Dioxide into Methanol

Autor:	Yoshiyuki Kojima, Kohji Omata, Tetsuo Umegaki
Rok vydání:	2021
Předmět:	inorganic chemicals 010405 organic chemistry Chemistry Oxide chemistry.chemical_element General Chemistry Zinc 010402 general chemistry 01 natural sciences Micelle Catalysis 0104 chemical sciences chemistry.chemical_compound Chemical engineering Pulmonary surfactant Specific surface area Methanol Mesoporous material
Zdroj:	Topics in Catalysis. 64:576-581
ISSN:	1572-9028 1022-5528
DOI:	10.1007/s11244-021-01430-3
Popis:	The present work has investigated influence of pore structure of silica coated on copper-zinc oxide-based catalyst for hydrogenation of carbon dioxide into methanol. For controlling the pore structure, micelles of a cationic surfactant, cethyltrimethylammonium bromide (CTAB), was used without and with a swelling agent, 1-dodecylamine, during coating silica on the commercial copper–zinc oxide-based catalyst. The pore structure depended on the amount of the surfactant and the swelling agent, and the specific surface area and the ratio of mesopores of the silica-coated catalyst significantly increased with adding 1-dodecylamine with the surfactant. The silica-coated catalyst prepared both with CTAB and 1-dodecylamine showed the significantly rapid evaporation of physisorbed water on the catalysts, and the property can reflect the catalyst’s high activity and stability for hydrogenation of carbon dioxide into methanol.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f71721be301b3bd7098eb99c4931b558 https://doi.org/10.1007/s11244-021-01430-3 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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