Emergency stopper for VCM suspension polymerization

Autor: S. M. Malmonge, L. R. Santos
Rok vydání: 1996
Předmět:
Zdroj: Journal of Vinyl and Additive Technology. 2:211-215
ISSN: 1548-0585
1083-5601
DOI: 10.1002/vnl.10127
Popis: Because of the exothermicity of reaction and the necessity of using active initiators for the vinyl chloride monomer (VCM) suspension polymerization reaction, a study was undertaken in order to choose the best polymerization inhibitor for emergency situations such as temperature runaway, power failures, and agitation system problems. The effect of triethylene glycol-bis3(3 terc-butyl-4-hydroxy-5-methyl phenyl) propionate (1) and N-nitrosophenylhydroxylamine ammonium salt (2) cited in the literature as free radical polymerization inhibitors on VCM suspension polymerization reactions is shown.
Databáze: OpenAIRE