Kinetics of propylene oxidation in the region of negative temperature coefficients of the rate

Autor:	A. A. Mantashyan, R. R. Grigoryan, S. D. Arsentiev
Rok vydání:	1985
Předmět:	Reaction rate Reaction rate constant Chemistry Kinetics Thermodynamics Maximum reaction rate Physical and Theoretical Chemistry Negative temperature Kinetic energy Catalysis
Zdroj:	Reaction Kinetics and Catalysis Letters. 29:187-193
ISSN:	1588-2837 0133-1736
DOI:	10.1007/bf02067967
Popis:	Kinetic regularities in the consumption of initial reactants and the accumulation of propylene oxidation products has been studied in the region of negative temperature coefficients of the maximum reaction rate (T=648–723 K). It has been revealed that for prolynene-enriched mixtures (C3H6:O2=3:1) at P-20.66 kPa, the reaction rate is practically independent of the temperature, whereas for poor mixtures (C3H6:O2=1:5) it decreases with increasing temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f6b1ff951d493e9e8b56a862b544ca35 https://doi.org/10.1007/bf02067967 Zobrazit plný text záznamu Full text from SpringerLink