ChemInform Abstract: Influence of N-Substituted Lactams on Acyclic Free Radical Based Hydrogen Transfer
Autor: | Mohammed Bencheqroun, Yvan Guindon |
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Rok vydání: | 2010 |
Předmět: | |
Zdroj: | ChemInform. 33 |
ISSN: | 1522-2667 0931-7597 |
Popis: | anti Relative stereochemistry is achieved in the hydrogen-transfer reaction of a lactam adjacent to the carbon-centered radical. The sense of diastereoselectivity is reversed using N-substituted lactams, and optimal results favoring syn reduced products are obtained with an α-methylbenzyl group and a Boc group. |
Databáze: | OpenAIRE |
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