ChemInform Abstract: Influence of N-Substituted Lactams on Acyclic Free Radical Based Hydrogen Transfer

Autor: Mohammed Bencheqroun, Yvan Guindon
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 33
ISSN: 1522-2667
0931-7597
Popis: anti Relative stereochemistry is achieved in the hydrogen-transfer reaction of a lactam adjacent to the carbon-centered radical. The sense of diastereoselectivity is reversed using N-substituted lactams, and optimal results favoring syn reduced products are obtained with an α-methylbenzyl group and a Boc group.
Databáze: OpenAIRE