Michael Adduct of Levoglucosenone and Cyclohexanone. Chiral Protection of Hydroxy Group in Stereoselective Transformations of Glycol Aldehyde

Autor:	Sh. M. Salikhov, D. R. Enikeeva, A. R. Tagirov, Farid A. Valeev, L. Kh. Fayzullina, Yu. S. Galimova
Rok vydání:	2018
Předmět:	chemistry.chemical_classification 010405 organic chemistry Organic Chemistry Hydroxy group Cyclohexanone 010402 general chemistry 01 natural sciences Aldehyde 0104 chemical sciences Adduct chemistry.chemical_compound chemistry Reagent Organic chemistry Stereoselectivity Ethylene glycol
Zdroj:	Russian Journal of Organic Chemistry. 54:726-733
ISSN:	1608-3393 1070-4280
DOI:	10.1134/s1070428018050093
Popis:	One of hydroxy groups of ethylene glycol was protected by hemiketal, obtained by treating Michael adduct of levoglucosenone and cyclohexanone with reagents system Me3SiCl‒NaI, while the other one was oxidized by Collins method. Stereocontrol in reactions of 1,2-addition to the obtained aldehyde was investigated (in reactions of Grignard, Henry, and Reformatsky).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f69d376eefb3fb938f93e72189dd745f https://doi.org/10.1134/s1070428018050093 Zobrazit plný text záznamu Plný text ve formátu PDF