Electrochemical behaviour of nitrobenzene in aqueous ethanol studied by differential pulse polarography

Autor:	Peter R. Fielden, Kerry J. Kippax-Davis, Madeleine Bully, John F. Alder, Adrian F.R. Watson, Anastasios Economou
Rok vydání:	1993
Předmět:	Detection limit Polarography Aqueous solution Ethanol Chemistry Inorganic chemistry Potassium nitrate Electrochemistry Biochemistry Analytical Chemistry Nitrobenzene chemistry.chemical_compound Hanging mercury drop electrode Environmental Chemistry Spectroscopy
Zdroj:	Analytica Chimica Acta. 284:13-19
ISSN:	0003-2670
DOI:	10.1016/0003-2670(93)80002-3
Popis:	Differential pulse polarographic studies of nitrobenzene in aqueous ethanol reveal complex behavior involving solvent composition, viscosity and pH. Both reduction potential and peak reduction current are dependent on all three parameters. Limits of detection of ca. 2 × 10−7 M and a linear working range up to 10−3 M nitrobenzene in ethanol—water (80:20) at pH 6 were recorded. No adsorptive accumulation of nitrobenzene onto the hanging mercury drop electrode employed was observed under any condition in the aqueous ethanol mixtures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f69c22b593edd38f30ee8e3196e98d56 https://doi.org/10.1016/0003-2670(93)80002-3 Zobrazit plný text záznamu