Synthesis and self-assembly of novel fluorous cationic amphiphiles with a 3,4-dihydro-2(1H)-pyridone spacer
| Autor: | Iveta Vesere, Marina Petrova, Baiba Skrivele, Oksana Petrichenko, Aiva Plotniece, Yelena Goncharenko, Gunars Duburs, Rufus Smits, Brigita Vigante |
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| Rok vydání: | 2011 |
| Předmět: |
Pyridinium bromide
Atomic force microscopy Organic Chemistry Cationic polymerization Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Dynamic light scattering Bromide Polymer chemistry Amphiphile Environmental Chemistry Organic chemistry Self-assembly Physical and Theoretical Chemistry |
| Zdroj: | Journal of Fluorine Chemistry. 132:414-419 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/j.jfluchem.2011.04.008 |
| Popis: | The synthesis of fluorous (highly fluorinated) 3,4-dihydro-2(1 H )-pyridone-5-carboxylate cationic amphiphiles have been described, where the dihydropyridone serves as a spacer and either a pyridinium bromide or a triphenylphosphonium bromide form the polar cationic head group. The in water self-assembled aggregates have been observed by atomic force microscopy (AFM) and dynamic light scattering (DLS). |
| Databáze: | OpenAIRE |
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