Photoelectron studies of boron compouds. Part 5.—Higher boron hydrides B4H10, B5H9and B10H14

Autor: Peter J. Roberts, Martyn F. Guest, D. Robert Lloyd, Norman Lynaugh
Rok vydání: 1975
Předmět:
Zdroj: J. Chem. Soc., Faraday Trans. 2. 71:1382-1394
ISSN: 0300-9238
DOI: 10.1039/f29757101382
Popis: The He I and He II photoelectron (p.e.) spectra of the title compounds are reported. Ab initio SCF-MO calculations have been carried out on diborane, pentaborane(9) and tetraborane(10) using a double zeta basis of Slater-type orbitals. Assignment of the spectra is made with the aid of these calculations and by correlation with the spectrum of diborane. The p.e. spectrum of pentaborane (9) shows marked differences from one previously reported.
Databáze: OpenAIRE