Experimental and theoretical investigation of intramolecular transformations of silicon-containing (haloalkyl)phosphorylated ureas and acylamides

Autor:	R. M. Kamalov, G. A. Chmutova, N. A. Khailova, S. A. Terent'eva, R. Kh. Bagautdinova, Lyudmila K. Kibardina, A. N. Pudovik, M. A. Pudovik
Rok vydání:	2006
Předmět:	Silicon Stereochemistry Chemistry Computational chemistry Intramolecular force Phosphorylation chemistry.chemical_element General Chemistry
Zdroj:	Russian Journal of General Chemistry. 76:376-380
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363206030078
Popis:	Silicon-containing chloromethylphosphorylated ureas undergo transformation involving evolution of chlorotrimethylsilane and formation of 1,3,4-oxazaphospholes. Their analogs, silicon-containing phosphorylated acylamides, transform in another way, viz. by β-cleavage to form the corresponding siloxyphosphonates. Quantum-chemical investigation of thermodynamic characteristics of these processes was carried out.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f665f0cb72a8e7c8104476cc8b763bd6 https://doi.org/10.1134/s1070363206030078 Zobrazit plný text záznamu Plný text ve formátu PDF