Origins of regioselectivity in Ni-catalyzed hydrofunctionalization of alkenes via ligand-to-ligand hydrogen transfer mechanism

Autor:	Han Gao, Lingfei Hu, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:8650-8653
ISSN:	1364-548X 1359-7345
Popis:	Energy decomposition analysis reveals that the regioselectivities of Ni-catalyzed LLHT with aryl- and alkyl-substituted alkenes are controlled by charge transfer and Pauli repulsion, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f647cb8fe69c4f69bcf8c6d863900e11 https://doi.org/10.1039/d2cc02691k Zobrazit plný text záznamu