Popis: |
Density, (ρ), and speed of sound, (u), from T = 288.15 to T = 308.15 K, and excess molar enthalpies, (hE) at T = 298.15 K, have been measured over the entire composition range for (methyl tert-butyl ether + 1-butanol + n-hexane). In addition, excess molar volumes, VE, and excess isentropic compressibility, κ s E , were calculated from experimental data. Finally, experimental excess enthalpies results are compared with the estimations obtained by applying the group-contribution models of UNIFAC (in the versions of Dang and Tassios, Larsen et al., Gmehling et al.), and DISQUAC. |