Crystal and Molecular Structure of a Platinum(II) Complex with β-Mercaptoethylamine Hydrochloride
| Autor: | Kh. I. Gasanov, A. N. Azizova, Sh. G. Kasumov, D. B. Tagiev, S. N. Osmanova |
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| Rok vydání: | 2018 |
| Předmět: |
Chemistry
Hydrochloride Ligand chemistry.chemical_element Biological activity Bridging ligand 02 engineering and technology 020501 mining & metallurgy Inorganic Chemistry Crystal chemistry.chemical_compound 0205 materials engineering Polymer chemistry Materials Chemistry Molecule Chelation Physical and Theoretical Chemistry Platinum |
| Zdroj: | Journal of Structural Chemistry. 59:188-192 |
| ISSN: | 1573-8779 0022-4766 |
| Popis: | The work describes in detail the structure of a coordination platinum(II) compound with the sulfur-and nitrogen-containing biologically active β-mercaptoethylamine ligand NH2CH2CH2SH which deprotonates during synthesis and acts simultaneously as a chelating and bridging ligand resulting in the formation of the hexanuclear [Pt6(NH2CH2CH2S)8]Cl4·3H2O complex of a non-cluster type. Depending on the conditions, in particular, medium pH, complexes with different nuclearities and hydration numbers can form in this system. |
| Databáze: | OpenAIRE |
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