The Diastereoselective Formation of Tetraalkoxy[4]resorcinarenes Derived from (-)-(2R)-2-Methoxy-2-phenylethanol and Proof of Absolute Configurations

Autor:	Harry Heaney, Philip C. Bulman Page, Eduardo Moreno, Yohan Chan, Matthew J. McGrath
Rok vydání:	2011
Předmět:	Steric effects chemistry.chemical_classification Resorcinol monobenzoate chemistry.chemical_compound Stereochemistry Chemistry Organic Chemistry Calixarene Phenol Physical and Theoretical Chemistry Ring (chemistry) Chirality (chemistry) Alkyl
Zdroj:	European Journal of Organic Chemistry. 2011:5347-5354
ISSN:	1434-193X
DOI:	10.1002/ejoc.201100733
Popis:	The preparation of optically pure (-)-3-[(2R)-2-methoxy-2-phenylethoxy] phenol from resorcinol monobenzoate and its conversion into diastereoisomeric tetraalkoxyresorcin[4]arenes together with proof of the absolute configurations of the products is reported. The results of the study indicate that diastereoselective ring closure of linear tetrameric intermediates is controlled by the steric demand of the alkyl group in the precursor 3-alkoxyphenol.
Databáze:	OpenAIRE
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