Band alignments of La x Al y O films on Si substrates grown by atomic layer deposition with different La/Al atomic ratios

Autor: Hongxia Liu, Shupeng Chen, Chenxi Fei, Feng Xingyao, Xing Wang, Lu Zhao
Rok vydání: 2016
Předmět:
Zdroj: Journal of Materials Science: Materials in Electronics. 28:4702-4705
ISSN: 1573-482X
0957-4522
Popis: La x Al y O films were grown on p-Si substrates by atomic layer deposition technique with different La and Al precursor pulse ratios. Then atomic concentrations and band alignments of the films were determined from X-ray photoelectron spectroscopy measurements. It was found that the bandgap and valence band offset increase synchronously with increasing Al composition, while the conduction band offset varies slightly. Furthermore, as the composition of Al increased, significant decrease in the gate leakage current for the metal–insulator–semiconductor capacitors using La x Al y O films as insulators was observed due to the formation of larger bandgaps and valence band offsets.
Databáze: OpenAIRE