ChemInform Abstract: Successive Electron Transfer Reaction of the Lithium Salt of 5-Methyl-5,10-dihydrophenazine Anion with 4-Nitrophenethyl Bromide via 4-Nitrostyrene

Autor:	Kaku Uehara, Akira Sugimoto, Hideyuki Maruyama, Tomohiro Adachi, Wataru Takahashi, Kazuhiko Mizuno
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Addition reaction Chemistry Dimethyl sulfoxide chemistry.chemical_element Salt (chemistry) Butane General Medicine Photochemistry Medicinal chemistry Ion chemistry.chemical_compound Electron transfer Bromide Lithium
Zdroj:	ChemInform. 31
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200006162
Popis:	The reaction of lithium salt of 5-methyl-5,10-dihydrophenazine anion with 4-nitrophenethyl bromide in 1,2-dimethoxyethane gave unexpected compounds, 1,2-bis[5-(10-methyl-5,10-dihydrophenazinyl)]-1-(4-nitrophenyl)ethane and 1,4-bis(4-nitrophenyl)-1,4-bis[5-(10-methyl-5,10-dihydrophenazinyl)]butane, while the reaction in dimethyl sulfoxide brought about the formation of 5-methyl-10-(4-nitrophenethyl)-5,10-dihydrophenazine. The successive electron transfer mechanism is proposed for the former reaction via 4-nitrostyrene.
Databáze:	OpenAIRE
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