A new lead Mo(IV) phosphate with a tunnel structure: Pb2Mo2O(PO4)2P2O7
| Autor: | André Leclaire, B. Raveau, J. Chardon |
|---|---|
| Rok vydání: | 2003 |
| Předmět: |
Inorganic chemistry
chemistry.chemical_element Condensed Matter Physics Phosphate Electronic Optical and Magnetic Materials Inorganic Chemistry chemistry.chemical_compound Crystallography Oxygen atom chemistry Molybdenum Materials Chemistry Ceramics and Composites Physical and Theoretical Chemistry Lone pair |
| Zdroj: | Journal of Solid State Chemistry. 172:412-416 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/s0022-4596(03)00018-5 |
| Popis: | A molybdenum (IV) phosphate containing lead, Pb 2 Mo 2 (PO 4 )2P 2 O 7 , has been synthesized for the first time. It crystallizes in the space group C 2/ c with a =14.098(1) A, b =14.187(2) A, c =6.5592(4) A and β =102.08(1)°. Its original tunnel structure, built up of Mo 2 O 11 bioctahedra, P 2 O 7 and PO 4 phosphate groups can be described from the assemblage of [Mo 4 P 4 O 24 ] ∞ ribbons interconnected through monophosphate groups. The stereoactivity of the 6 s 2 lone pair of Pb 2+ , which is surrounded by nine oxygen atoms, is discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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