A 13C nuclear magnetic resonance study of cyclobutadieneirontricarbonyl-substituted carbonium ions
| Autor: | C. Scott Eschbach, Perry C. Reeves, Dietmar Seyferth |
|---|---|
| Rok vydání: | 1976 |
| Předmět: |
Electron density
Chemistry Organic Chemistry Carbon-13 NMR Biochemistry Ion Inorganic Chemistry Metal chemistry.chemical_compound Nuclear magnetic resonance Cyclobutadieneiron tricarbonyl Carbonium ion visual_art Materials Chemistry visual_art.visual_art_medium Cyclobutadiene Hydroxymethyl Physical and Theoretical Chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 104:363-372 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)91381-0 |
| Popis: | The 13 C NMR spectra of (hydroxymethyl)-, (α-hydroxyethyl)- and (α-hydroxybenzyl)cyclobutadieneiron tricarbonyl (in CDCl 3 ) and of their derived carbonium ions (in concentrated H 2 SO 4 ) are reported. The data suggest extensive donation of electron density from the metal, via the cyclobutadiene unit, to the exocyclic, electron-deficient carbon atom, thus giving highly stabilized carbonium ions. |
| Databáze: | OpenAIRE |
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