Autor: |
Haifeng Liu, Wanxiang Zhang, Weisen Liu, Guangcai Zhang |
Rok vydání: |
2002 |
Předmět: |
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Zdroj: |
Journal of Physics: Condensed Matter. 14:11401-11404 |
ISSN: |
0953-8984 |
DOI: |
10.1088/0953-8984/14/44/489 |
Popis: |
The equations of state of hydrogen and deuterium are studied using the ideal mixing model. An effective potential with many-body effects has been taken into account. The Helmholtz free energy of a molecule is calculated by employing pure fluid perturbation theory, and the expression for the free energy of an atom is modelled following a similar formula in liquid metal perturbation theory. The Helmholtz free energy for a system with dissociation is given by combining the molecular free energy and atomic free energy. The equation of state obtained this way is in good agreement with experiment. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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