Potential dependent surface Raman spectroscopy of single wall carbon nanotube films on platinum electrodes

Autor: Paulo Sérgio Medeiros dos Santos, Paola Corio, Shin Grace Chou, Victor W. Brar, Ge. G. Samsonidze, Mildred S. Dresselhaus
Rok vydání: 2003
Předmět:
Zdroj: Chemical Physics Letters. 370:675-682
ISSN: 0009-2614
DOI: 10.1016/s0009-2614(03)00157-x
Popis: The analysis of the resonance Raman spectra of single-walled carbon nanotubes in an electrochemically controlled aqueous H2SO4 environment using different laser excitation energies shows major reversible and irreversible differences in the main vibrational features regarding their intensities, lineshapes, and frequencies for different applied potentials. These differences arise from the electrochemically induced changes in the occupation of electronic states for metallic and semiconducting nanotubes.
Databáze: OpenAIRE