Formation of uncondensed binuclear heterocyclic compounds in the thio-claisen rearrangement of heteroaromatic sulfides

Autor:	S. M. Panov, S. A. Nepogod'ev, V. F. Sizoi, Alexander V. Anisimov, E. A. Viktorova
Rok vydání:	1983
Předmět:	Claisen rearrangement chemistry.chemical_classification Sulfide Chemistry Organic Chemistry Thio Organic chemistry Ring (chemistry) Medicinal chemistry
Zdroj:	Chemistry of Heterocyclic Compounds. 19:1072-1075
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00505755
Popis:	Allyl hetaryl Sulfides with an allyl fragment that is part of a heteroaromatic ring undergo a [3,3]-sigmatropic rearrangement when they are heated in various solvents, as a result of which uncondensed binuclear heterocyclic compounds are formed. On the basis of kinetic data it was shown that the inclusion of the vinyl or allyl fragment of a sulfide in the composition of the heteroaromatic ring hinders the rearrangement more, the higher the aromatic character of the heteroring.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f594165a9f25d2908b2d559a7e24d9cf https://doi.org/10.1007/bf00505755 Zobrazit plný text záznamu Full text from SpringerLink