Catalyst-free alkanoylation of aromatic rings via arylstannanes. Scope and limitations

Autor:	Alicia B. Chopa, Marcos J. Lo Fiego, Maria T. Lockhart
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Aryl Organic Chemistry Regioselectivity Aromaticity Biochemistry Catalysis Inorganic Chemistry Direct route chemistry.chemical_compound chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Alkyl
Zdroj:	Journal of Organometallic Chemistry. 694:3674-3678
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2009.07.019
Popis:	The reaction of alkanoyl chlorides with arylstannanes in 1,2-dichlorobenzene (180 °C) is a simple and direct route for the catalyst-free and regioselective synthesis of tertiary alkyl aryl ketones in good to excellent isolated yields (55–77%). Nevertheless, under similar conditions, reactions carried out with alkanoyl chlorides bearing α-hydrogens render only the product of protodestannylation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f570f6336ba96c7bd8630267c391a23f https://doi.org/10.1016/j.jorganchem.2009.07.019 Zobrazit plný text záznamu Full Text from ScienceDirect