Preparation of Polymer-Mineral Nanocomposites Based on Vinyl Monomers and Dispersed Inorganic Oxides
| Autor: | Yaroslav Kovalskyi, Olena Aksimentyeva, Nataliya Oshchapovska, Volodymyr Dutka |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
organic chemicals
Butyl acrylate Radical polymerization 020206 networking & telecommunications 02 engineering and technology Benzoyl peroxide 021001 nanoscience & nanotechnology Peroxide chemistry.chemical_compound Adsorption Monomer chemistry Polymerization Chemical engineering 0202 electrical engineering electronic engineering information engineering medicine General Earth and Planetary Sciences 0210 nano-technology Methyl acrylate General Environmental Science medicine.drug |
| Zdroj: | Advances in Chemical Engineering and Science. 11:18-28 |
| ISSN: | 2160-0406 2160-0392 |
| DOI: | 10.4236/aces.2021.111002 |
| Popis: | The polymer-mineral composites were synthesized using vinyl monomers styrene, methyl acrylate, and butyl acrylate with nano dispersed oxides Fe2O3, Cr2O3, V2O5 and SiO2 in the presence of benzoyl peroxide and other peroxide initiators. Benzoyl peroxide adsorption on Fe2O3, Cr2O3, and V2O5 surfaces was studied. The adsorption parameters were found: adsorption-desorption equilibrium constants, maximum adsorption, and the area occupied by the molecule benzoyl peroxide on the surface of the adsorbent. The molecular weights of the polymers in the composites and the degree of grafting of the macromolecules of the polymer to the surface of oxides were studied. It has been found that the surface of the dispersed oxides influences the rate of thermal decomposition of the peroxide initiators and the polymerization parameters of the vinyl monomers. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|