One-pot synthesis of Cu-modified HNb3O8 nanobelts with enhanced photocatalytic hydrogen production
| Autor: | Cong Lin, Fengjuan Pan, Yaming Qiu, Xiaoge Wang, Junliang Sun, Yifang Zhao, Jianhua Lin, Jian Li, Ligang Wang, Yanquan Yang |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Photocurrent
Materials science Renewable Energy Sustainability and the Environment One-pot synthesis 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Exfoliation joint 0104 chemical sciences Nanomaterials law.invention Chemical engineering law Photocatalysis General Materials Science Calcination 0210 nano-technology Photocatalytic water splitting Hydrogen production |
| Zdroj: | Journal of Materials Chemistry A. 6:10769-10775 |
| ISSN: | 2050-7496 2050-7488 |
| DOI: | 10.1039/c8ta02766h |
| Popis: | Ultrathin nanomaterials have aroused much attention because of their enhanced photocatalytic activities. However, conventional exfoliation methods require a complex preparation procedure, and the intercalated cationic organic compounds are difficult to remove. Herein, HNb3O8 nanobelts were successfully prepared via a one-pot hydrothermal route by using POM precursors. With the aid of acetic acid, Cu ions were easily loaded through a one-pot synthesis, and they significantly enhanced the photocatalytic water splitting performance (8 times higher than that of unmodified nanobelts). Based on the XPS results, we found that the Cu ions had mixed oxidation states of Cu+/Cu2+, and the ratio did not change after calcination at 350 °C, indicating that some of the Cu+ ions were inserted between the layers. The role of Cu in promoting hydrogen evolution activities was attributed to the improvement in the separation of photo-induced carriers and the photo-to-electron conversion efficiency; these observations were confirmed by the analyses of photocurrent response and photoluminescence. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|