Autor:	Dai-Zheng Liao, Yu-Guo Fan, Zong-Hui Jiang, Tian-Jian Li, Peng Cheng, Hui-Zhong Kou, Shi-Ping Yan, Jinkui Tang, Geng-Lin Wang, Wie-Ming Bu, Dong-Zhao Gao
Rok vydání:	2001
Předmět:	Magnetism Inorganic chemistry Metals and Alloys Ionic bonding chemistry.chemical_element 1 3-Diaminopropane Crystal structure Inorganic Chemistry chemistry.chemical_compound Crystallography Chromium chemistry Materials Chemistry Antiferromagnetism Ferricyanide Organometallic chemistry
Zdroj:	Transition Metal Chemistry. 26:457-460
ISSN:	0340-4285
DOI:	10.1023/a:1011080110767
Popis:	Two CrIII–FeIII complexes, K2[Cr(salen)(H2O)][Fe(CN)6]·H2O (1) and [trans-Cr(tn)2Cl2]3[Fe(CN)6]·6H2O (2), have been prepared. Crystal structure determination shows that complex (2) possesses an ionic salt structure. General physical measurements and magnetic studies indicate that (1) assumes a cyanide-bridged dinuclear structure, and that the CrIII–FeIII magnetic coupling through the cyanide bridge is antiferromagnetic, which can be rationalized by the overlap of magnetic orbitals of the same symmetry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f51cea5852e4f29a3fa78aeb5b4bd6ef https://doi.org/10.1023/a:1011080110767 Zobrazit plný text záznamu Full text from SpringerLink