H-atom abstraction kinetics in solids influenced by free radical decay during their accumulation

Autor:	B.V. Bol'shakov, A.B. Doktorov, A.I. Burshtein, V.A. Tolkatchev
Rok vydání:	1979
Předmět:	chemistry.chemical_compound chemistry Radical Kinetics General Physics and Astronomy Irradiation time Methanol Physics::Chemical Physics Physical and Theoretical Chemistry Photochemistry Abstraction (mathematics)
Zdroj:	Chemical Physics Letters. 64:113-115
ISSN:	0009-2614
DOI:	10.1016/0009-2614(79)87288-7
Popis:	The effect of irradiation time on the monomolecular nonexponential decay kinetics of free radicals has been investigated theoretically and experimentally. Equations are derived for the accumulation and dark-decay kinetics. These are in agreement with experimental data obtained for H-atom abstraction reactions by CH 3 radicals in methanol glass at 77 K.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f508e6a28195da65f504222fa5e5bb2c https://doi.org/10.1016/0009-2614(79)87288-7 Zobrazit plný text záznamu