Secoorthosiphols A–C: three highly oxygenated secoisopimarane-type diterpenes from Orthosiphon stamineus

Autor:	Suresh Awale, Kazuhiko Taira, Shigetoshi Kadota, Seikichi Shimoji, Yasuhiro Tezuka
Rok vydání:	2002
Předmět:	chemistry.chemical_compound chemistry biology Stereochemistry Organic Chemistry Drug Discovery Orthosiphon stamineus Diterpene biology.organism_classification Biochemistry
Zdroj:	Tetrahedron Letters. 43:1473-1475
ISSN:	0040-4039
Popis:	Three new highly oxygenated 2,3-secoisopimarane-type diterpenes, named secoorthosiphols A (1), B (2) and C (3), have been isolated as extremely minor constituents from the aerial parts of the Orthosiphon stamineus from Okinawa. A unique unprecedented structural feature of such a ring A opened system in newly isolated compounds was encountered for the first time in isopimarane-type diterpenes. Secoorthosiphol C (3) represents the first example of a biogenetically unique and unconventional secoisopimarane-type diterpene having a cyano group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f4f173e66e64c65a467fabca01244697 https://doi.org/10.1016/s0040-4039(02)00037-0 Zobrazit plný text záznamu Full Text from ScienceDirect