Nickel-catalyzed carbonylation of arylboronic acids with DMF as a CO source

Autor:	Jian Lu, Yang Li, Zhao-Tie Liu, Yao-Yu Wang, Zhong-Wen Liu, Bo Wang, Dong-Huai Tu, Ju-You Lu
Rok vydání:	2017
Předmět:	010405 organic chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Metal Nickel chemistry Transition metal visual_art visual_art.visual_art_medium Organic chemistry Carbonylation Bond cleavage
Zdroj:	Organic Chemistry Frontiers. 4:569-572
ISSN:	2052-4129
DOI:	10.1039/c7qo00001d
Popis:	By using N,N-dimethylformamide (DMF) as a CO source, the cheap metal nickel-catalyzed carbonylation of arylboronic acids was demonstrated as an efficient and facile protocol for the synthesis of diaryl ketones. Results indicated that NiBr2·diglyme was the best pre-catalyst among the investigated transitional metal salts, and excellent yields were achieved via C–H and C–N bond cleavage.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f4e99dd42242c373fe0f2283fe11c7c0 https://doi.org/10.1039/c7qo00001d Zobrazit plný text záznamu