Preparation of ABNO on Scale and Analysis by Quantitative Paramagnetic NMR

Autor:	Guoyue Zhou, Zhiguo J. Song, Ryan D. Cohen, Lushi Tan
Rok vydání:	2018
Předmět:	Paramagnetism Materials science Sensitivity test 010405 organic chemistry Organic Chemistry Inorganic chemistry Proton NMR Physical and Theoretical Chemistry 010402 general chemistry Chemical purity 01 natural sciences 0104 chemical sciences Catalysis
Zdroj:	Organic Process Research & Development. 22:1257-1261
ISSN:	1520-586X 1083-6160
DOI:	10.1021/acs.oprd.8b00191
Popis:	A practical, safe, and scalable synthesis of the stable nitro-oxide radical catalyst ABNO was developed. This process is chromatography-free and avoids the Wolff–Kishner reduction. 1H NMR data for this paramagnetic compound were obtained that allowed an assessment of its chemical purity. Impact sensitivity test data for solid ABNO are also reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f4e493b5750e33b140e6d49fe52d773d https://doi.org/10.1021/acs.oprd.8b00191 Zobrazit plný text záznamu