Purification of Oleylamine for Materials Synthesis and Spectroscopic Diagnostics for trans Isomers
| Autor: | Alexa R. Carollo, Callum R. Douglass, Anna C. Curtis, Dmitry Baranov, David M. Jonas, Michael J. Lynch, Alina M. Mateo-Tejada |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
General Chemical Engineering Lead chloride Inorganic chemistry Infrared spectroscopy 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Mole fraction 01 natural sciences 0104 chemical sciences NMR spectra database symbols.namesake chemistry.chemical_compound chemistry Oleylamine Materials Chemistry symbols 0210 nano-technology Raman spectroscopy Cis–trans isomerism Perovskite (structure) |
| Zdroj: | Chemistry of Materials. 31:1223-1230 |
| ISSN: | 1520-5002 0897-4756 |
| DOI: | 10.1021/acs.chemmater.8b04198 |
| Popis: | Oleylamine is widely used in nanomaterial and metal-halide perovskite synthesis. Impurities in commercially available oleylamine reagents are identified, purification procedures are explained, beneficial effects on lead chloride/oleylamine mixtures are documented, and impacts on materials synthesis are discussed. Suspensions of 0.12 mole fraction PbCl2, PbBr2, and PbI2 in purified, dried, and filtered oleylamine were found to form clear solutions upon heating to 100 °C. The infrared, Raman, and NMR spectra of oleylamine and a common trans impurity present in literature reference IR spectra are presented. |
| Databáze: | OpenAIRE |
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