Application of the electro-optic Kerr effect to investigation of the intermolecular H-bond

Autor:	V.V. Prezhdo, Oleg V. Prezhdo
Rok vydání:	2000
Předmět:	Kerr effect Hydrogen bond Chemistry Organic Chemistry Complex formation Intermolecular force Thermodynamics Analytical Chemistry Inorganic Chemistry Dipole Computational chemistry Moment (physics) Spectroscopy Equilibrium constant
Zdroj:	Journal of Molecular Structure. 526:115-130
ISSN:	0022-2860
DOI:	10.1016/s0022-2860(00)00446-4
Popis:	The intermolecular H-bond plays an important role in chemical and biological systems and processes. This review considers various aspects of the application of the electro-optic Kerr effect in the investigation of the intermolecular H-bond. Current approaches to the determination of structures of H-bonded molecular complexes are described. From the measurements of the electro-optic and molar Kerr constants of the complexes and their individual components these methods produce the basic parameters of the H-bonded complexes, including the complex formation equilibrium constant (K) and the H-bond dipole moment (μH). The importance of a new parameter, namely, the structural additive difference of the molar Kerr constants (ΔmK)S is illustrated. The prospects of future progress in the studies of the intermolecular H-bond by the electro-optic methods are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f4983a9d164a1687766a0fcced1f8b11 https://doi.org/10.1016/s0022-2860(00)00446-4 Zobrazit plný text záznamu Full Text from ScienceDirect