ChemInform Abstract: First Total Synthesis of Tenuifolin via PIFA-Mediated Oxidative Biaryl Coupling
Autor: | Ziyuan Li, Ling-Yi Kong, Changhua Tang, Jinyi Xu, Hequan Yao, Xiaoming Wu, Yiyun Wang |
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Rok vydání: | 2011 |
Předmět: | |
Zdroj: | ChemInform. 42 |
ISSN: | 0931-7597 |
Popis: | The first total synthesis of a sesquiterpenoid, tenuifolin, was achieved in seven linear steps. Phenyliodine(III) bis(trifluoacetate) (PIFA) mediated oxidative biaryl coupling was employed as a key step to construct the central seven-membered ring with a double bond. The double bond formation was also exploited. |
Databáze: | OpenAIRE |
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