Diborane heterolysis and P(v ) reduction by Ph3PO coordination to magnesium
| Autor: | Nasir A. Rajabi, Anne-Frédérique Pécharman, Mary F. Mahon, Claire L. McMullin, Michael S. Hill |
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| Rok vydání: | 2019 |
| Předmět: |
Phosphine oxide
010405 organic chemistry Magnesium Metals and Alloys chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Heterolysis Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Reduction (complexity) chemistry.chemical_compound chemistry Reagent Materials Chemistry Ceramics and Composites Density functional theory Triphenylphosphine oxide Diborane |
| Zdroj: | Chemical Communications. 55:9035-9038 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c9cc04294f |
| Popis: | Reaction of a magnesium diboranate complex with triphenylphosphine oxide provides a terminal magnesium boryl, which is itself a potent reagent for the deoxygenative reduction of Ph3PO. Computational analysis with density functional theory (DFT) indicates that B–B bond activation results from initial coordination of the PO bond of the phosphine oxide to magnesium. |
| Databáze: | OpenAIRE |
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