ChemInform Abstract: Stereoconvergent Synthesis of Chiral Allylboronates from an E/Z Mixture of Allylic Aryl Ethers Using a 6-NHC-Cu(II) Catalyst

Autor:	Jin Kyoon Park, Brian A. Ondrusek, D. Tyler McQuade, Hershel H. Lackey
Rok vydání:	2011
Předmět:	Allylic rearrangement chemistry.chemical_compound chemistry Aryl Absolute configuration Ether General Medicine Borylation Medicinal chemistry Catalysis
Zdroj:	ChemInform. 42
ISSN:	0931-7597
Popis:	The six-membered N-heterocyclic carbene-copper complex IQC catalyzes the asymmetric borylation of both the (E)- and (Z)-isomer of an allylic m-nitrophenyl ether to give the α-substituted allylboronate with the same absolute configuration.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f489c9cab85cf708792073835962c4aa https://doi.org/10.1002/chin.201128175 Zobrazit plný text záznamu Plný text